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Dialin

From Wikipedia, the free encyclopedia
Dialin
Names
Preferred IUPAC name
1,2-Dihydronaphthalene
Other names
Bicyclo[4.4.0]deca-1,3,5,7-tetraene; Δ1-Dialin; 1,2-Dialin[citation needed]
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.006.532 Edit this at Wikidata
UNII
  • InChI=1S/C10H10/c1-2-6-10-8-4-3-7-9(10)5-1/h1-3,5-7H,4,8H2 checkY
    Key: KEIFWROAQVVDBN-UHFFFAOYSA-N checkY
  • c2ccc1c(C=CCC1)c2
Properties
C10H10
Molar mass 130.190 g·mol−1
Density 0.993 g/cm3
Melting point −8.5 °C (16.7 °F; 264.6 K)
−85.1·10−6 cm3/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Dialin (1,2-dihydronaphthalene) is a hydrocarbon with the chemical formula C10H10. The compound is chiral. It is related to naphthalene by the addition of two H atoms. It is a colorless oil. The compound can be prepared by dehydration of tetrahydronaphthol.[1]

Cryogenic irradiation interconverts dialin with [10]‑annulene.[2][3]

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Bibliography

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  1. ^ Korstanje, Ties J.; Jastrzebski, Johann T. B. H.; Klein Gebbink, Robertus J. M. (2010). "Catalytic Dehydration of Benzylic Alcohols to Styrenes by Rhenium Complexes". ChemSusChem. 3 (6): 695–697. Bibcode:2010ChSCh...3..695K. doi:10.1002/cssc.201000055. PMID 20468027.
  2. ^ Masamune S.; Seidner, R. T. (1969). "[10]Annulenes". Journal of the Chemical Society D: Chemical Communications (10): 542. doi:10.1039/c29690000542. ISSN 0577-6171.
  3. ^ Kemp-Jones, A. V.; Masamune S. (1973). "The monocyclic 10π-electron system". In Nozoe Tetsuo; Breslow, Ronald; Hafner, Klaus; Itô Shô; Murata Ichiro (eds.). Topics in Nonbenzenoid Aroma­tic Chemistry. Vol. I. Tokyo/New York: Hirokawa Publishing, on behalf of Halsted Press, a division of John Wiley & Sons. p. 122. ISBN 0-470-65155-5 – via the Internet Archive.