| Nº |
Picture |
Name |
President |
Term in office
|
| Holders of the title "Wife of the President"
|
| 1º |
 |
Mercedes Jijón |
Juan José Flores |
1830–1834
|
| 2º |
 |
Baltazara Calderón de Rocafuerte |
Vicente Rocafuerte y Bejarano |
1835–1839
|
| (1º) |
 |
Mercedes Jijón |
Juan José Flores |
1839–1845
|
|
 |
María Rosa Icaza |
José Joaquín de Olmedo (Head of the Provisional Government) |
1845–1845
|
| 3º |
|
Juana Andrade Fuente Fría |
Vicente Ramón Roca |
1845–1849
|
|
 |
Carmen Salinas de la Vega |
Manuel de Ascazubi y Matheu (Vice-president, in charge of the Government) |
1849–1850
|
| 4º |
 |
Tomasa Carbo y Noboa |
Diego Noboa |
1850–1851
|
| 5º |
 |
Teresa Jado |
José María Urvina y Viteri |
1851–1856
|
| 6º |
 |
Carmen de Santistevan y Avilés |
Francisco Robles Garcia |
1856–1859
|
| 7º |
|
Rosa Ascázubi y Matheu |
Gabriel García Moreno |
1859–1865
|
|
|
Widower |
Rafael Carvajal (Vice-president, in charge of the Government) |
1865–1865
|
| 8º |
|
María Antonia Andrade |
Jeronimo Carrion y Palacio |
1865–1867
|
|
|
Juana Arteta y Garzon |
Pedro José de Arteta (Vice-president, in charge of the Government) |
1867–1868
|
|
|
Single |
Javier Espinosa y Espinosa |
1868–1869
|
|
 |
Mariana del Alcázar y Ascasubi |
Gabriel García Moreno (Interim President) |
1869–1869
|
|
 |
Carmen Salinas de la Vega |
Manuel de Ascásubi y Matheu (Interim constitutional President) |
1869–1869
|
| 9º |
 |
Mariana del Alcazar y Ascasubi |
Gabriel García Moreno |
1869–1875
|
|
|
|
Francisco Xavier León y Franco (Vice-president, in charge of the Government) |
1875–1875
|
|
|
Isabel Valdivieso y Carcelén de Guevara |
José Javier Eguiguren (Min. of Finance, in charge of the Government) |
1875–1875
|
| 10º |
|
Rosa Lucía Moscoso Cardenas |
Antonio Borrero y Cortázar |
1875–1876
|
| 11º |
 |
Marieta de Veintemilla |
Ignacio de Veintemilla y Villacis |
1876–1883
|
|
 |
Jesús Dávila Heredia |
Luis Cordero Crespo (1st President of the Pentavirato) |
1883
|
|
|
Antonia Chiriboga y Muñoz |
Rafael Pérez Pareja (2nd President of the Pentavirato) |
1883
|
| 12º |
|
Pastoriza Marquez de la Plata y Plaza |
José María Plácido Caamaño |
1883–1888
|
|
|
Leticia Escobar y Salvador |
Pedro José Cevallos (Vice-president, in charge of the Government) |
1895–1895
|
| 13º |
|
Leonor Ruiz de Apodaca |
Antonio Flores Jijón |
1888–1892
|
|
|
Widower (Jesús Davila Heredia) |
Luis Cordero Crespo |
1892–1895
|
|
|
Manuela Quiñones Perez |
Vicente Lucio Salazar (Vice-president, in charge of the Government) |
1895–1895
|
| 14º |
 |
Ana Paredes Arosemena |
Eloy Alfaro Delgado |
1895–1901
|
| 15º |
 |
Avelina Lasso |
Leónidas Plaza y Gutiérrez |
1901–1905
|
| 16º |
|
Carmen Coello Alvarez |
Lizardo García Sorroza |
1905–1906
|
| (14º) |
 |
Ana Paredes Arosemena |
Eloy Alfaro Delgado |
1906–1911
|
|
|
Rosa Elena Larrea y Gomez de la Torre |
Carlos Freile Zaldumbide (President of the Senate, in charge of the Government) |
1911–1911
|
| 17º |
 |
Lastenia Gamarra Menéndez |
Emilio Estrada Carmona |
1911
|
|
|
Rosa Elena Larrea y Gomez de la Torre |
Carlos Freile Zaldumbide (President of the Senate, in charge of the Government) |
1911–1912
|
|
|
Victoria Malo German |
Francisco Andrade Marín (President of the Congress, in charge of the Government) |
1912–1912
|
|
|
Piedad Roca Marcos |
Alfredo Baquerizo Moreno (President of the Senate, in charge of the Government) |
1912–1912
|
| (15º) |
 |
Avelina Lasso |
Leónidas Plaza y Gutiérrez |
1912–1916
|
| 18º |
|
Piedad Roca Marcos |
Alfredo Baquerizo Moreno |
1916–1920
|
| 19º |
 |
Esther Concha Torres |
José Luis Tamayo |
1920–1924
|
| 20º |
|
Victoria Monsalve Cardenas |
Gonzalo Córdova y Rivera |
1924–1925
|
|
|
Does not exist |
Provisional Government |
1925–1926
|
| 21º |
 |
Laura Carbo Núñez |
Isidro Ayora Cueva |
1926–1931
|
|
|
Lucy Lopez y Williams |
Luis Larrea Alba (Secretary of State, in charge of the Government) |
1931–1931
|
|
|
Piedad Roca Marcos |
Alfredo Baquerizo Moreno (President of the Senate, in charge of the Government) |
1931–1932
|
|
|
Manuela Gomez de la Torre y Nájera |
Carlos Freile Larrea (Secretary of State, in charge of the Government) |
1932–1932
|
|
|
Maria Elena Valenzuela y Plaza |
Alberto Guerrero Martínez (President of the Senate, in charge of the Government) |
1932–1932
|
| 22º |
|
Francisca Torres Lascano |
Juan de Dios Martínez Mera |
1932–1933
|
|
|
|
Abelardo Montalvo (President of the Senate, in charge of the Government) |
1933–1934
|
| 23º |
|
Esther Silva Burbano |
José María Velasco Ibarra |
1934–1935
|
|
|
Single |
Antonio Pons (Secretary of State, in charge of the Government) |
1935–1935
|
|
|
Adelina Espinosa García |
Federico Páez (Interim President) |
1935–1937
|
|
|
Mariana Calderón Alava |
Alberto Enríquez Gallo (Supreme Chief) |
1937–1938
|
|
|
Ana Maria Bustamante |
Manuel María Borrero (Interim President) |
1938
|
| 24º |
|
Judith Perez Davalos |
Aurelio Mosquera Narváez |
1938–1939
|
|
 |
Elena Yerovi Matheu |
Carlos Arroyo del Río (President of the Senate, in charge of the Government) |
1939
|
|
|
Rosario Galarza Arizaga |
Andres Fernandez de Cordova (President of the Congress, in charge of the Government) |
1939–1940
|
|
|
|
Julio Enrique Moreno (President of the Senate, in charge of the Government) |
1940
|
| 25º |
 |
Elena Yerovi Matheu |
Carlos Arroyo del Río |
1940–1944
|
|
|
Does not exist |
Provisional Government |
1944
|